Okeke, I. SObodo, R. MEze, C. N.Orji, M. PAgwu, K. KUbachukwu, A. AEzema, F. I2025-05-182023978-323-85883-0http://repository.futminna.edu.ng:4000/handle/123456789/1988Materials with high dielectric constants are essential in the control and advancement of electronics and electrical power systems. The dielectric properties of materials majorly include dielectric constants (ꜫo) and loss tangent (tan ẟ), and for a material to be considered a very good dielectric material, it needs greater ꜫo, lower tan ẟ and reduced leakage current (J). Inorganic mixed transition oxides (MTMOS) ceramics composites have shown huge potential than the transition metal oxide because they constitute two or more metal elements with different expansion coefficients that give rise to synergistic effects. MTMOs ceramics composites are mostly found with spinel structure such as normal spinel structure (NSS) and inverse spinel structure (IVS). Several synthesis techniques have been used in formulation of MTMOs ceramic composites. Their dielectric properties have been modified considerately by altering its morphology, use of modifying agent, and high calcination temperatures. In this chapter, we summarized MTMOs major structure type synthesis technique that have been successfully used in preparation of MTMOs, the dielectric properties of MTMOs and basis of surface modification in MTMOs as well as its effect in the dielectric properties.ensurface modificationceramic compositesdielectric propertiesMTMOsBook chapter