Chemical Engineering
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Chemical Engineering
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Item Transesterification of waste frying oil to methyl ester using activated Carbon supported Mg-Zn oxide as solid-base catalyst(1st International Engineering Conference (IEC) Federal University of Technology, Minna, Nigeria, 2015) Olutoye, M. A.; Eterigho, Elizabeth Jumoke; Suleiman, B.; Adeniyi, O. D.; Mohammed, I. A.; Musa, U.An activated carbon-supported Mg-Zn catalyst (Mg-Zn/AC) was prepared by using co-precipitation combined with incipient wetness impregnation methods. The catalyst structure was characterized by powder X-ray diffraction (XRD), N2 adsorption-desorption, Fourier transform infrared spectroscopy (FTIR), its microstructure was studied by the use of scanning electron microscopy (SEM)and the catalytic performance toward synthesis of methyl esters from waste frying oil (WFO) was investigated. The properties studied provided insight into the catalytic performance of the catalyst whereby the large surface area and pore volume of the support facilitated the distribution of metal particles and high dispersion of metals. The optimum reaction conditions were obtained by varying parameters such as methanol to oil ratio, catalyst loading, temperature and time. Under the conditions of reaction time of 5 h, temperature, 150 °C and catalyst dosage of 2.5 wt%, the methyl ester yield of >86% was achieved using 64 g of WFO, 38 g of methanol. The results showed that Mg-Zn/AC catalyst presented efficient activity during the transesterification reaction and is a promising heterogeneous catalyst for the production biodiesel fuel from vegetable oil feedstock.Item Agriculture by-product: A Source for the Production of Biogas(Asian Journal of Engineering and Technology, 2015-04) Eterigho, Elizabeth Jumoke; Farrow T. S.Agricultural by-products, rice husk and maize bran were used anaerobically in this study to produce biogas. The suitability of these substrates as source of biogas and comparative study of the two substrates were investigated. Various analyses were carried out to determine the ash content, moisture content, volatile solids and fixed carbon content present in each substrate. The biogas produced was analysed using a gas chromatograph and was found to contain oxygen, nitrogen and methane in various proportions. From the results of the analyses, rice husk produced a larger volume of gas than the maize bran, though the maize bran's gas has a higher content of methane than that of rice husk (about 60.90%). The experiment was carried out under mesophilic temperature range and a pH of 6.2 - 7.6Item Alternative Production of Fatty Acid Methyl Esters from Triglycerides using Sulphated Zirconia(Nigerian Journal of Technological Research (NJTR), 2013) Eterigho, Elizabeth Jumoke; Lee, J. G. M.; Harvey, A. P.Sulphated zirconia (SZ) was synthesized using two different methods with the same molar ratio (1:6) of reactants: (1) the direct mixing of ZrOCl.8H20 and (NH4),SO4, designated as SZ,; and (2) via the conventional wet-precipitation method with a molar ratio of l:6 rather than the conventional 15 ml H2SO4 to Ig of Zr(OH)4, denoted by (SZ,). The catalysts physiochemical properties were precisely characterized by FTIR, SEM, X-ray diffraction, EDX, XPS, and Py-DRIFTS techniques. The two methods of preparation with same molar ratio of sulphating agents led to sulphated zirconia that exhibited different morphological and structural properties in terms of specific surface areas, thermal stability, acid sites, and surface sulphate. The catalysts activity was tested in thermocatalytic cracking of triglyceride; a direct conversion process for fatty acid methyl esters (biodiesel). The SZ not only exhibited higher conversion of triglycerides but higher fatty acid methyl esters (FAMEs) yield of approximately 59% after 3h as compared to SZ, (32%). In addition, the sulphated zirconia, SZ, was selective towards unsaturated esters whereas SZ, was selective towards saturated esters.Item Development of Mathematical Model for the Assessment of Hydrogen Sulphide Pollutant in the Air(Journal of Research in Engineering (JRIE), 2008) Olutoye, M. A.; Eterigho, Elizabeth JumokeThis work is aimed at developing a mathematical model to determine the concentration of Hydrogen Sulphide pollutant in air from the gas flare of a refinery. To achieve this, experimental data on concentration of Hydrogen Sulphide from Kaduna refinery and petrochemical company Nigeria were collected and the dispersion model was developed based on Gaussian distribution principle. The simulation of the model was carried out using visual basic programming. It was observed from the simulated result that the gas dispersion model developed for Hydrogen Sulphide showed a remarkable agreement with the dispersion pattern, and agrees with the experimental results with a correlation co efficient of 0.98. Thus, the model can be used to determine the safe distance for human habitation from an industrial area and the refinery in particular.Item Catalytic Cracking of Tryglyceride by Sulphated Zirconia for Fatty Aciud Methyl Ester with High Selectivity(American Institute of Chemical Engineers (AIChE) Annaul Conference meeting, Minneapolis, MN, United State, 2010-07-21) Eterigho, Elizabeth Jumoke; Lee, Jon G. M.; Harvey, Adam P.Conventional wet-precipitation method was used to synthesis sulphated zirconia using two different molar ratios of sulphating agents. (1) the first was using a molar ratio of 1: 45 of ZrOCl2.8H20 impregnated with 1 M H2SO4, (wp) and (2) a molar ratio of 1: 6 was used for the modified conventional wet-precipitation method, (wp). The properties of both catalysts were examined by various techniques: EDX, XPS, FTIR, SEM, XRDP, Py-DRIFTS and BET nitrogen adsorption techniques. The variation in the molar ratio of the sulphating agent used during preparation led to sulphated zirconia that exhibited different properties in terms of specific surface areas, acid sites, thermal stability and surface sulphate. Both catalysts were catalytically active for triglycerides cracking for fatty acid methyl esters in a thermocatalytic reaction. The SZ not only exhibited higher conversion of triglycerides but higher FAMEs yield, approximately 50% after 3 h, as compared to SZ2 (39%). Interestingly, SZ1 was selective towards unsaturated esters whereas SZ2 was towards saturated esters.