Browsing by Author "YUSUF Abubakar Sadiq"

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A review of coating tin oxide electron transport layer for optimizing the performance of perovskite solar cells
(Chemistry of Inorganic Materials Volume 6, August 2025, 100100, 2025-04-10) YUSUF Abubakar Sadiq; Ahmad Alhaji Abubakar; Isah Kimpa Mohammed; Umaru Ahmadu; Kasim Uthman Isah
Perovskite solar cells (PSCs) have recently emerged as a transformative technology in the photovoltaic sector, drawing considerable attention due to their rapid advancements in power conversion efficiency (PCE), which now exceeds 26.7 %. This efficiency level places them in direct competition with conventional silicon-based solar cells. A key element in ensuring the high performance of PSCs is the charge transport layer (CTL), particularly the electron transport layer (ETL). The ETL plays a crucial role by efficiently collecting photo-generated electrons from the perovskite layer and transferring them to the transparent conductive oxide electrode. Among the ma- terials used for ETLs, tin oxide (SnO 2) stands out for its wide band gap, excellent optical transparency, superior carrier mobility, and remarkable chemical stability. Additionally, SnO2 can be deposited at low temperatures, making it ideal for mass production and adaptable for applications such as flexible devices. Despite its inherent advantages, the overall performance and quality of the ETL, and thus the device itself, are heavily influenced by the fabrication process. This study reviews recent approaches to fabricating SnO 2 ETLs in PSCs, with a focus on optimizing efficiency and long-term stability
Bound state solutions of the generalized shifted Hulthén potential
(Indian Journal of Physics Publishing model Hybrid, 2020-01-09) YUSUF Abubakar Sadiq; C. O. Edet; P. O. Okoi; P. O. Ushie; P. O. Amadi
In this study, we obtain an approximate solution of the Schrödinger equation in arbitrary dimensions for the generalized shifted Hulthén potential model within the framework of the Nikiforov–Uvarov method. The bound state energy eigenvalues were computed, and the corresponding eigenfunction was also obtained. It is found that the numerical eigenvalues were in good agreement for all three approximations scheme used. Special cases were considered when the potential parameters were altered, resulting in Hulthén potential and Woods–Saxon Potential, respectively. Their energy eigenvalues expressions agreed with the already existing literature. A straightforward extension to the s-wave case for Hulthén potential and Woods–Saxon potential cases is also presented.
Effect of Al Dope with ZnO Electron Transport Layer in Perovskite Solar Cells Using SCAPs 1-D Simulation
(Nigerian Journal of Physics (NJP)ISSN online: 3027-0936ISSN print: 1595-0611, 2024-06-01) YUSUF Abubakar Sadiq; Ramalan, A. M; Abubakar, A. A; Mohammed,I.K; Ibrahim, S. O; Adamu, F. E; Ahmadu, U; Isah, K. U
Perovskite solar cells have shown exceptional performance and significant advancements in solar cell efficiency. For perovskite solar cells to conduct electrons and generate current, one of the key components is the substance known as the electron transport layer (ETL). Using the SCAPS 1D modelling program, ZnO: Al was used in this instance as the ETL material in a perovskite solar cell. Because of its interaction with the perovskite material, the ZnO: Al ETL demonstrated high cell efficiency. The performance of the ZnO: Al-doped-based solar cell achieved a PCE as high as 23.5%. In the meanwhile, the greatest cell performance in terms of enhancing the charge transport mechanism and raising cell efficiency was shown by perovskite solar cells doping the ETL with Al and having the right layer thickness. Thus, throughout the manufacturing process, the parameters used in this study may serve as a guide.
EFFECT OF ELECTRON TRANSPORT LAYERS, INTERFACE DEFECT DENSITY AND WORKING TEMPERATURE ON PEROVSKITE SOLAR CELLS USING SCAPS 1-D SOFTWARE
(EAST EUROPEAN JOURNAL OF PHYSICS. 1. 332-341 (2024), 2023-12-30) YUSUF Abubakar Sadiq; A.M. Ramalan; A.A. Abubakar; I.K. Mohammed
Perovskite solar cells have garnered significant attention from solar cell researchers due to their potential for achieving high efficiency, primarily attributed to their exceptional Electron Transport layer (ETL). One of the key elements of perovskite solar cells for transporting electrons to generate current is the ETL material. Moreover, there is a promising avenue for enhancing stability and reducing fabrication costs by substituting the transport layer. In this study, TiO2 and SnO2 were used as ETL materials in the architecture of perovskite solar cells for a comparative analysis between two devices featuring distinct structures: TiO2/CH3NH3PbI 3 /Spiro- OMeTAD and SnO 2/CH3NH3PbI 3/Spiro-OMeTAD. To evaluate the performance of each electron transport layer (ETL), the SCAPS 1D tool was employed. The investigation involved varying the thickness of the electron transport layers, interface defect density and working temperature, allowing for a comprehensive assessment of key parameters such as voltage at open circuit (Voc), short circuit current density (Jsc), fill factor (FF), and overall efficiency (PCE%). Remarkably, when employing SnO2 as the ETL, the achieved efficiency stands at 10.10 %. In contrast, utilizing TiO2 as the ETL yields a slightly higher efficiency of 12.84%. These findings underline the nuanced influence of transport layer materials on the overall performance of perovskite solar cells
Effect of Natural Dye Co-Sensitization on the Performance of Dye-Sensitized Solar Cells (DSSCS) Based on Anthocyanin and Betalain Pigments Sensitisation
(European Journal of Applied Sciences 9 (3): 140-146, 2017 ISSN 2079-2077, 2017-01-01) YUSUF Abubakar Sadiq; K.U. Isah; B.J. Jolayemi
Dye-sensitized solar cells (DSSCs) were prepared using natural pigments containing anthocyanin and betalain extracted from Flame tree and Bougainvillea glabra flowers respectively as sensitizers. The dyes were used as lone sensitizers exploring anthocyanin and betalain separately and as co-sensitizers exploring the combined anthocyanin and betalain (water extract) and combined anthocyanin and betalain (ethanol extract) separately. The effects of the sensitizers on the performance of the DSSCs were investigated, the study reveals that all the cells possess comparable values of V of about 0.55 0.1 V. However, of the two lone sensitisers,oc betalain based device gave a better efficiency of 0.21% while anthocynin based device achieved 0.17 %, this is attributed to their different anchoring functional groups. The, combined anthocyanin and betalain dyes (water extract) had the highest conversion efficiency of 0.26 % suggesting dye synergic absorption effect as a result of co-sensitisation, the lower efficiency of 0.24 %) achieved by combined anthocyanin and betalain (ethanol extract) is attributed to the contributory effect of the extraction solvents
Optimizing the resistivity of colloidal SnO2 thin films by ion implantation and annealing
(Surfaces and Interfaces Volume 55, December 2024, 105325, 2024-11-01) YUSUF Abubakar Sadiq; Martin Markwitz; Zhan Chen; Maziar Ramezani; John V. Kennedy; Holger Fiedler
Tin oxide (SnO2) is a critical material for a wide range of applications, such as in perovskite solar cells, gas sensors, as well as for photocatalysis. For these applications the transparency to visible light, high availability, cheap fabrication process and high conductivity of SnO2 benefits its commercial deployment. In this paper, we demonstrate that the resistivity of widely colloidal SnO2 can be reduced by noble gas ion beam modification. After low energy argon implantation with a fluence of 4×1015 at.cm−2 at 25keV and annealing at 200°C in air, the resistivity of as-deposited film was reduced from (178±6)μΩcm to (133±5)μΩcm, a reduction of 25%. Hall effect measurements showed that the primary cause of this is the increase in carrier concentration from (8.1±0.3)×1020 cm−3 to (9.9±0.3)×1020 cm−3. Annealing at 200°C resulted in the removal of defect clusters introduced by implantation, while annealing at 300°C resulted in the oxidation of the films, increasing their resistivity. The concentration of oxygen vacancy defects can be controlled by a combination of low energy noble gas ion implantation and annealing, providing promising performance increases for potential applications of SnO2 where a low resistivity is crucial. Graphical abstract
SCAPS-1D ANALYSIS OF NON-TOXIC LEAD-FREE MASnI 3 PEROVSKITE-BASED SOLAR CELL USING INORGANIC CHARGE TRANSPORT LAYERS
(EAST EUROPEAN JOURNAL OF PHYSICS. 3. 447-455 (2024), 2024-08-19) YUSUF Abubakar Sadiq; Matthew I. Amanyi; Eghwubare Akpoguma; Stephen O. Eghaghe; James Eneye; Raymond M. Agaku; Lilian C. Echebiri; Emmanuel U. Echebiri; Emmanuel O. Ameh; Chinyere I. Eririogu; Nicholas N. Tasie; Anthony C. Ozurumba; Eli Danladi
Perovskite solar cells (PSCs) have gained a lot of attention due to their high efficiency and low cost. In this research paper, a methylammonium tin iodide (CH3NH3SnI 3) based solar cell was simulated using a one-dimensional solar cell capacitance simulation (SCAPS-1D) tool. The SCAPS-1D tool is based on Poisson and the semiconductor equations. After thorough investigation, the initial device presents the following parameters; power conversion efficiency (PCE)=15.315%, fill factor (FF)=64.580%, current density (Jsc)=29.152 mA/cm 2, and open circuit voltage (Voc)=0.813 V. The effect of absorber and ETL thicknesses were explored systematically. The performance of the simulated device was significantly influenced by the thickness of the absorber and ETL. The optimized absorber thickness was 0.5 μm and the ETL thickness was 0.02 μm, giving rise to an optimized PCE of 15.411%, FF of 63.525%, Jsc of 29.812 mA/cm2, and Voc of 0.814 V. Additionally, the effect of temperature on the optimized device was evaluated and found that it affects the performance of the device. This model shows the prospect of CH3NH3SnI 3 as a perovskite material to produce toxic-free environment-friendly solar cells with high efficiency.
SCAPS-1D simulated organometallic halide perovskites: A comparison of performance under Sub-Saharan temperature condition
(Heliyon 10 (2024) e29599, 2024-04-13) YUSUF Abubakar Sadiq; Anthony C. Ozurumba; Nnamdi V. Ogueke; Chinyere A. Madu; Philibus M. Gyuk; Ismail Hossain
Heliyon 10 (2024) e29599 Available online 15 April 2024 2405-8440/© 2024 The Author(s). Published by Elsevier Ltd. This is an open access article under the CC BY-NC license (http://creativecommons.org/licenses/by-nc/4.0/).Research article SCAPS-1D simulated organometallic halide perovskites: A comparison of performance under Sub-Saharan temperature condition Anthony C. Ozurumba a,*, Nnamdi V. Ogueke b, Chinyere A. Madu c, Eli Danladi d, Chisom P. Mbachu e, Abubakar S. Yusuf f, Philibus M. Gyuk g, Ismail Hossain h a Africa Center of Excellence in Future Energies and Electrochemical Systems, Federal University of Technology, Owerri, Imo State, Nigeria b Department of Mechanical Engineering, Federal University of Technology, Owerri, Imo State, Nigeria c Department of Physics, Federal University of Technology, Owerri, Imo State, Nigeria d Department of Physics, Federal University of Health Sciences, Otukpo, Benue State, Nigeria e Department of Electrical/Electronic Engineering, Federal University of Technology, Owerri, Imo State, Nigeria f Department of Physics, Federal University of Technology, Minna, Niger State, Nigeria g Department of Physics, Kaduna State University, Kaduna, Kaduna State, Nigeria h School of Natural Sciences and Mathematics, Ural Federal University, Yekaterinburg, 620000, Russia A R T I C L E I N F O Keywords: OHP SCAPS-1D Perovskites Temperature Graphene Sub-sahara A B S T R A C T Photovoltaic technology has been widely recognized as a means to advance green energy solu- tions in the sub-Saharan region. In the real-time operation of solar modules, temperature plays a crucial role, making it necessary to evaluate the thermal impact on the performance of the solar devices, especially in high-insolation environments. Hence, this paper investigates the effect of operating temperature on the performance of two types of organometallic halide perovskites (OHP) - formamidinium tin iodide (FASnI3) and methylammonium lead iodide (MAPbI3). The solar cells were evaluated under a typical Nigerian climate in two different cities before and after graphene passivation. Using a one-dimensional solar capacitance simulation software (SCAPS-1D) program, the simulation results show that graphene passivation improved the conversion effi- ciency of the solar cells by 0.51 % (FASnI3 device) and 3.11 % (MAPbI3 device). The presence of graphene played a vital role in resisting charge recombination and metal diffusion, which are responsible for the losses in OHP. Thermal analysis revealed that the MAPbI3 device exhibited an increased fill factor (FF) in the temperature range of 20–64 ◦C, increasing the power conversion efficiency (PCE). This ensured that the MAPbI3 solar cell performed better in the city and the season with harsher thermal conditions (Kaduna, dry season). Thus, MAPbI3 solar cells can thrive excellently in environments where the operating temperature is below 65 ◦C. Overall, this study shows that the application of OHP devices in sub-Saharan climatic conditions is empirically possible with the right material modification
Trend Analysis of Temperature in Gombe State Using Mann Kendall Trend Test
(Journal of Scientific Research & Reports, 2018-10-11) YUSUF Abubakar Sadiq; U. U. Alhaji; C. O. Edet; Celestine O. Oche; E. P. Agbo
This paper presents the trend analysis of temperature in Gombe State using Mann-Kendall trend test. The annual average of Maximum and Minimum Temperature data was obtained from the Nigerian Meteorological Agency (NIMET), Gombe State. In order to determine the nature of the trend and significance level, Mann-Kendall trend test and Sen’s estimate were employed. From this study, it was found out that Maximum and Average temperature exhibit positive Kendall’s Z value which indicates an upward trend and also imply increasing trend over time. The Test statistic ( ) for maximum and average temperatures are 4.38 and 4.43 respectively. This indicates that there is a significant increase in the trend at 5% level of significance since (p-values (0.0001) <0.05). However, the Z value for minimum temperature (1.59) shows a positive trend but not significant at 5% significant level since the p-value is greater than the significant level (p-value (0.107)>0.05). It can be inferred from both Mann- Kendall and Sen’s Slope that there is the tendency of increment in temperature. This could be due to the impact of climate change and can lead to weather extremes in the study area. It is therefore recommended that the variability of temperature should be monitored in order to minimize its effects on human activities.