Browsing by Author "Onyia, A. I"

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    Chemically Deposited Doped Titanate Ternary Metal Oxide Thin Films Via Spray Pyrolysis Route-Preparation, Characterization and Solar Cell Application Analysis
    (4th Africa Nano Conference and Workshop, 2021-07) Eze, C. N.; Onyia, A. I; Nnabuchi, A. I
    Spray pyrolysis method of deposition is a simple, cheap, low cost and conventional method that gives uniform deposition. With this motivation, a simple approach of spraying ZnTiO3 nanoparticles on a substrate is reported. The approach occurs with ternary metal oxide and is environmentally friendly. This follows the quest to further improve the physical and chemical properties of ternary metal oxide which has become noticeable in recent times. The crystallization temperature of ZnTiO3 was 2000C. Among other investigations the SEM result shows a perovskite structure-like morphology. Further characterization performed on the thin film for the structural aspect which gives XRD of the thin film shown on the diffractogram is in agreement with the standard diffraction of ZnTiO3 which is identified as tetragonal structure. UV-Vis absorption spectroscopy was also used to characterize the final product and the spectra indicated that the absorbance obviously increased in the visible light region with absorption peak at about 209 nm and with optical band gap which infers that it has potential application in solar energy devices.
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    Synthesis and Characterization of Chemically Deposited Doped Stannate Ternary Metal Oxide Thin Films and Their Solar Energy Applications
    (4th Africa Nano Conference and Workshop, 2021-07) Eze, C. N.; Onyia, A. I; Nnabuchi, M. N
    Nano structured ternary metal oxide thin film like ZnSnO4 have receive much attention in the last decades owing to their unique properties rendering them suitable for wide range of applications. ZnSnO4 were grown by the chemical spray pyrolysis method. Home made spray pyrolysis technique is employed to prepared thin films. ZnSnO4 film was deposited on glas substrate using aqueous solution of zinc acetate dehydrate (Zn (CH3COO)2.2H2O and Tin (11) Chloride dehydrate or Stanic Chloride pentahydrate, SnCl2.5H2O as precursor at temperature of 2000C. the concentration of Zinc was varied from 0.001 to 0.005 while that of Tin was at 0.5. The product was annealed at 1hr at 2000C to improve its crystallinity. Various investigative techniques like XRD, SEM, EDX, UV-Visible, Raman spectroscopy analysis were carried out to find out the structural, morphological, spectroscopic and other properties of the ternary oxide thin film. The synthesized ZnSnO4 is of average crystalline size nano flowered having transmittance which increases with increase in wavelength. It has various band gaps which makes it find its application in photocatalysis and DSSCs (photoanode).Self