Browsing by Author "Eterigho Elizabeth J."

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    Characterization of Kaolin Clay from Kutigi and Its De-Aluminated form for Catalysts Development towards Economic growth of Nigeria
    (APWEN International conference (a division of NSE) Kano, 2017-09) Omale, Friday David; Eterigho Elizabeth J.; Baaki, Monica Alueshima
    Kaolin, a product of natural hydrated aluminium silicate which has undergone refinement is a type of clay material which is usually in powder form and is whitish in colour. It is a soft sedimentary rock which has light weight and a chalk-like appearance. The chemical analysis of the kaolin obtained from Kutigi in Niger State by X-ray fluorescence shows that the clay is mainly composed of silica and alumina which are 50.94% and 32.93% respectively. The de-alumination of the clay by action of H2SO4 shows that a large percentage of the silica in the clay was removed. X-ray fluorescence of the de-aluminated clay shows a higher alumina content (76.236%) and silica (1.095%) indicating its removal.
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    Harnessing Alternative Technology for the Sustainability of Biodiesel Production
    (Iranica Journal of Energy and Environment, 2016-11-17) Eterigho Elizabeth J.; Farrow, T. S.; Agbajelola, D. O.; Ejejigbe, S. E.; Harvey, A.P.
    Biofuel, a renewable energy is mainly produced by transesterification of fatty acids either in presence of enzyme or catalysts. The transesterification relies on the use of either strong base or strong acid homogeneous catalysts for effective performance; but, homogeneous catalysts are associated with a variety of technical hurdles that limit their use for biodiesel production. Although there have been recent developments in heterogeneous catalysts for biodiesel production via transesterification; the separation of methyl ester (FAMEs) from crude glycerol and alcohol recovery are still major hindrances. A possible alternative could be the use of solid acid catalysts in thermo-catalytic cracking of triglycerides. Sulphated zirconia catalyst was evaluated for thermo-catalytic cracking of triglycerides at a relatively low temperature (270oC) and atmospheric pressure. The catalyst was found to be active toward cracking vegetable oils to methyl esters. The catalyst at this temperature exhibited different selectivity towards formation of saturated and unsaturated methyl esters. The catalyst yield of methyl esters under these conditions was 58% while 80% of the product being unsaturated. This opens up the possibility of controlling the degree of saturation of the methyl ester product by catalyst choice, to produce more or less saturated fuels for different markets. The range of products from gases to middle distillates and the unique selectivity for saturated and unsaturated esters may be a significant process advantage of this form of catalytic cracking. An important long chain unsaturated alcohol (1- Heptatriacotanol) was also identified. The unsaturated alcohol is known as an industrial chemical.