Browsing by Author "Ejejigbe, S. E."

Now showing 1 - 2 of 2

Harnessing Alternative Technology for the Sustainability of Biodiesel Production
(Iranica Journal of Energy and Environment, 2016-11-17) Eterigho Elizabeth J.; Farrow, T. S.; Agbajelola, D. O.; Ejejigbe, S. E.; Harvey, A.P.
Biofuel, a renewable energy is mainly produced by transesterification of fatty acids either in presence of enzyme or catalysts. The transesterification relies on the use of either strong base or strong acid homogeneous catalysts for effective performance; but, homogeneous catalysts are associated with a variety of technical hurdles that limit their use for biodiesel production. Although there have been recent developments in heterogeneous catalysts for biodiesel production via transesterification; the separation of methyl ester (FAMEs) from crude glycerol and alcohol recovery are still major hindrances. A possible alternative could be the use of solid acid catalysts in thermo-catalytic cracking of triglycerides. Sulphated zirconia catalyst was evaluated for thermo-catalytic cracking of triglycerides at a relatively low temperature (270oC) and atmospheric pressure. The catalyst was found to be active toward cracking vegetable oils to methyl esters. The catalyst at this temperature exhibited different selectivity towards formation of saturated and unsaturated methyl esters. The catalyst yield of methyl esters under these conditions was 58% while 80% of the product being unsaturated. This opens up the possibility of controlling the degree of saturation of the methyl ester product by catalyst choice, to produce more or less saturated fuels for different markets. The range of products from gases to middle distillates and the unique selectivity for saturated and unsaturated esters may be a significant process advantage of this form of catalytic cracking. An important long chain unsaturated alcohol (1- Heptatriacotanol) was also identified. The unsaturated alcohol is known as an industrial chemical.
Sulphated Zirconia Catalyst Prepared from Solid Sulphates by Non-aqueous Method
(Iranica Journal of Energy and Environment (IJEE), 2017) Eterigho, Elizabeth J. Eterigho; Farrow, T. S.; Ejejigbe, S. E.
Non-crystallinesulphated zirconia catalysts were synthesised by a non-aqueous and non-conventional method. The effect of varying the molar ratio of sulphating agent to zirconium source was also investigated. The samples were characterized by X-ray diffraction, Energy Dispersive X-ray (EDX), Infra-red Spectroscopy (IR), X-ray Photoelectron Spectroscopy (XPS). The surface acidity was measured by the Pyridine-DRIFTS (Diffuse Reflectance Infrared Fourier Transform Spectroscopy) technique. The structural and textural properties of the sulphated zirconia were studied. The EDX and XPS profiles suggested that both sulphated zirconia catalysts have similar zirconia and sulphate structures; however, both catalysts were amorphous. Deconvolution of their XPS O 1s spectra showed that the samples contained both oxide oxygen of zirconium and sulphate oxygen, which sample I showed a higher amount of sulphate oxygen. Adsorption of pyridine into the samples indicated that the higher amounts of Brönsted acid sites are presented in sample I with lower amount of sulphate during preparation. This opens up the possibility of controlling the degree and type of active sites on a catalyst by the amount of sulphate used for preparation. Sulphated zirconia catalyst with higher activity properties was achieved via a non-aqueous, environmentally friendly method. The zirconia catalyst has great contribution towards energy production which is used for preparation and transesterification of fatty acids for production of biodiesel