Browsing by Author "Bisiriyu, Muhammad Taoheed"

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An Assessment of Groundwater Quality in Tudun Fulani, Niger State, Nigeria
(Sule Lamido University Journal of Science and Technology (SLUJST), 2020-12) Bisiriyu, Muhammad Taoheed; Ganiyu, Mustapha Adekomi; Audu, Lawal Idris; Abdullahi, AbdulHakam Safiu; Animashaun, Iyanda Murtala
groundwater is the main source of drinking water in Tudun Fulani community in Bosso, Niger State, Nigeria. Objective: this study was conducted to assess the physicochemical and heavy metal characteristics of groundwater used for drinking and other domestic purposes in the area with a view to determining its suitability for these purposes. Method: twelve water samples comprising of seven hand-dug wells and five boreholes were collected from different locations in the area. Physicochemical parameters (pH, turbidity, electrical conductivity, total dissolved solids (TDS), total suspended solids (TSS), total solids (TS), alkalinity, total hardness, chloride) and heavy metals (lead, manganese, copper and iron) contents were determined using standard methods. Results: the results showed that the pH, electrical conductivity, TDS, TSS, TS turbidity, alkalinity, total hardness and chloride ranged between 5.72 – 7.32, 252.5 – 1098 μS/cm, 58 – 11.35 mg/L, 0.001 – 0.108 mg/L, 1.05 – 7.33 NTU, 10.60 - 104.20 mg/L, 26.6 – 170.2 mg/L, and 28.17 – 86.9 mg/L, respectively. The heavy metal analysis revealed lead, manganese, copper, and iron to range between 0.001-0.009 mg/L, 0.01-0.28 mg/L, 0.010 - 0.050 mg/L and 0.100 – 0.430 mg/L, while manganese and lead were not detected in one and six of the samples, respectively. Conclusion: the values of the parameters analysed in this study were below and within the permissible limits set by the World Health Organisation (WHO) for most of the water samples investigated; hence, the groundwater is suitable for drinking and for other life-supporting activities. However, only four samples (W1,W5 W6, and W7) were within the range of 100 - 300 mg/L set by WHO for total hardness. In addition, the pH values of water samples W4, W5, B4, and B5 were below the recommended standard, while the electrical conductivity of W5, turbidity of W3, W5 and iron contents of W2 and W7 were above the maximum limit set by WHO. Therefore, it is recommended that the indiscriminate discharge of wastes be checked in locations of W2 and W7 as high iron content in drinking water poses serious health risks to consumers.
COMPARATIVE STUDY OF BIOETHANOL PRODUCTION FROM IRISH AND SWEET POTATO PEELS BY HYDROLYSIS AND FERMENTATION PROCESSES USING Saccharomyces cerevisiae
(FUW Trends in Science & Technology Journal, www.ftstjournal.com, 2021-10-12) Bisiriyu, Muhammad Taoheed; Habu, Christopher; Amos, Pigweh Isa; Amunike, Perpetual Chiamaka; Isah, Abdulrahman Adamu
The quest for green and sustainable sources of energy has led to various studies on the production of biofuels such as bioethanol from different agricultural materials. This study presents a comparative analysis of bioethanol produced from Sweet and Iris potato using simultaneous saccharification and fermentation (SSF). 5.00, 10.00, and 15.00 g each of the Sweet and Irish potato peels were hydrolyzed using dilute acid (5% H2SO4). A dried baker’s yeast strain (Saccharomyces cerevisiae) was subsequently introduced to ferment the substrates for 7 days. The bioethanol yield, average bioethanol yield, density, and proximate composition of the substrates were determined. The yield of bioethanol for Sweet potato peels at 5.00, 10.00, and 15.00 g were 43.50, 64.50 and 82.00 cm3 while for Irish potato peel at 5.00, 10.00 and 15.00 g were 22.00, 41.50, and 59.00 cm3, respectively. The average bioethanol yield for Sweet potato and Irish potato peels were 63.33 and 40.83%, while the density for Sweet and Irish potato peels were 0.853 and 0.891 g/cm3, respectively. The proximate composition for Sweet potato peel was 5.10±0.01% moisture, 4.00±0.023% ash, 2.99 ± 0.044% lipid, 3.50±0.03% fiber, 7.00±0.05% protein, and 77.41±0.01% carbohydrate while for Irish potato peel were 8.75± 0.63% moisture, 3.55± 0.05% ash, 4.48± 0.03 lipid, 4.50± 0.55% fiber, 4.38± 0.67% protein and 74.34±0.15% carbohydrate. Therefore potato peels can be harness as a potential feedstock for bioethanol production with Sweet potato peel having a higher yield of bioethanol compared to Irish potato due to higher carbohydrate content.
Ga(iBu)3 supported on meso H-ZSM-5: Effect of Si/Al ratio on the activity and selectivity in propane aromatization
(Elsevier Catalysis Communications, 2024) Jessy, Abou Nakad; Firth, Daniel; Bisiriyu, Muhammad Taoheed; Szeto, Kai. C.; Merle, Nicolas; De Mallmann, Aimery; Gauvin, Regis M.; Delevoye, Laurent; Olsbye, Unni; Taoufik, Mostafa
The grafting of Ga(iBu)3 on a series of meso-H-ZSM5, prepared by desilication-dealuminiation(Si/Al=25,50,100,200,∞) has been studied. The materials were characterized by IR, solid- state NMR, BET, ICP and EXAFS. Ga(iBu)3 reacts selectively with silanol groups, yielding a monopodal surface species in the mesopores. Importantly, the Bronsted acidic sites remain intact in the micropores, as IR and 1H MAS-NMR revealed. These materials can be regarded as bifunctional catalysts, containing isolated Ga sites and Bronsted sites in proximity, suitable for propane aromatization. Catalytic investigations show high activity and selectivity toward aromatics, toward aromatics, particularly for low Si/Al ratios.
Physicochemical and bacteriological evaluation of sachet water sold in Minna metropolis, Niger State, Nigeria
(International Journal of Advanced Chemistry Research, 2023-06-12) Mohammed, Ibrahim; Bisiriyu, Muhammad Taoheed; Salau, Rasaq Bolakale; Suleiman, Asmau Omowumi; Abdullahi, Hamidu; Ogbiko, Cyril; Rople, Gungshik John; Abdullah, Rabiat Lawal
Physical assessment of the package labels (product name, manufacturing address, National Agency for Food and Drug Administration (NAFDAC) registration number, manufacturing and expiry date and batch number on the labeling) and quality evaluation of the physicochemical and bacteriological properties of the water samples collected was assess and analyzed in relation to level of compliance with package water recommended standards. Four (4) clusters were considered in which three samples were collected from vendors in each cluster making up a total of twelve (12) samples. Physical examinations revealed 100% compliance to standards in terms of the product name, manufacturing address and NAFDAC registration number but zero percent compliance for manufacturing and expiry dates but only about 17% of the samples had a batch number on the labeling. The physiochemical parameters show appreciable compliance to standards with an ambient temperature of 28 °C, pH range of 6.5 to 8.5 and conductivity values ranged between 104.67 - 225.67 µS/cm still lower compared to the maximum range of 1000 µS/cm by Nigerian Industrial Standard (NIS). Samples turbidity results recorded zero value for SWA1, SWB2, SWC3, SWE5, SWG5, SWH6, SWI7, SWJ8 and SWK9 except for sample SWD10, SWF11, and SWL12 with a turbidity of 2.00, 2.00 and 3.00 NTU, respectively and were still within NIS/WHO limit of 5 NTU. Total dissolved solids (TDS) values ranged from 70.20 - 171.67 mg/L but still within the threshold limit of 500 mg/L recommended by NIS. The bacteriological parameters gave total bacterial count (TBC) ranged between 1 - 16.50 cfu/cm3 accounting for SWB2=2.00, SWC3=1.50, SWD4=2.00, SWE5=1.00, SWF6=5.50, SWG7=4.00, SWH8=5.00, SWI9=13.00, SWJ10=8.50, SWK11=16.50,and SWL12=16.00 cfu/cm3 above the WHO limit of zero cfu/cm3 except SWA with 0.00 cfu/cm3 in conformity with the standard limit while TCC ranged from 1-1.50 cfu/cm3 for SWC3=1.50, SWD4=1.00, SWE5=1.00, SWG7=1.00, SWH8=1.50 and SWK11=1.50 cfu/cm3 which is all above the WHO limit of 0.00 cfu/cm3except six samples (SWA1, SWB2, SWF6, SWI9, SWJ10 and SWL12) having 0.00 cfu/cm3 accounting for 50% samples compliance with the tolerance limit. The concentration of Pb, Zn, Fe, and Cr in the samples was below the WHO/SON tolerant level of 0.01 mg/L for Pb, 5 mg/L for Zn, 0.3 mg/L for Fe and 0.05 mg/L for Cr except for samples SWF6, SWG7, and SWJ10 with Pb concentration of 0.04, 0.032, and 0.050 mg/L respectively, above permissible limits of WHO/SON. The corrosion of pipes used in the water processing may account for the Pb concentration hence, regular assessment of the sachet water products should be ensured by the regulating agencies to promote both water and health safety.
Quality Evaluation of Bottled Water Packaged within Niger State, Nigeria
(Nigerian Research Journal of Chemical Sciences, 2020) Bisiriyu, Muhammad Taoheed; Ganiyu, Mustapha Adekomi; Ogwuche, Nelson Edache; Koleola, Abidemi Adedayo; Salau, Rasaq Bolakale
Ten different brands of bottled water were procured from different regions of Niger State, Nigeria for this study. The labeling information, temperature, pH, turbidity, electrical conductivity, total hardness, chloride, alkalinity, lead, copper, manganese and iron contents of the water samples were determined using standard methods. The investigation revealed that the temperature, pH, electrical conductivity, total hardness, chloride and alkalinity of the samples ranged between 26.5+0.50–28.0+0.00 oC, 6.20+0.09–7.33+0.30, 13.5+1.50– 317.5+1.50 µScm-1, 13-125 mg/L, 2.89 - 31.36 mg/L and 5-60 mg/L, respectively. Lead and copper were not detected in all the samples except SB10 with 0.01 mg/L of copper. Similarly, manganese was detected in six samples at concentrations between (0.02-0.08 mg/L) while iron ranged between 0.01-0.16 mg/L). The physical, chemical and heavy metals composition of the water samples complied with World Health Organization (WHO) and Standard Organization of Nigeria (SON) permissible limits for drinking water except the pH of one sample (SB8) that was below the permissible limit. However, 60% of the brands had no manufacturing and expiry dates on their label as required by the Nigeria’s National Agency for Food and Drug Administration and Control (NAFDAC). Therefore, periodic evaluation and monitoring by concerned agencies should be intensified to ensure that bottled water producers in the state strictly adhere to the standard operating procedures
Receptor Modeling Application on Surface Water Quality and Source Apportionment
(2016-02-05) Animashaun, Iyanda Murtala; Ahaneku, Isiguzo Edwin; Busari, Musa Bola; Bisiriyu, Muhammad Taoheed
There is a need for regular monitoring of river water quality to determine specific pollutants in order to aid amelioration schemes. In this study, Principal Component Analysis (PCA) was applied to eighteen water quality parameters; pH, conductivity, dissolved oxygen(DO), turbidity, temperature, total dissolved solids (TDS), total solids (TS), total hardness (TH), biochemical oxygen demand (BOD), carbon dioxide (CO2), ammonia (NH3), nitrate (NO3-), chloride (Cl-), lead (Pb), iron (Fe), chromium (Cr), copper (Cu) and manganese (Mn) to identify major sources of water pollution of river Asa. The generated Principal Components (PCs) were used as independent variables and the water quality index (WQI) as the dependent variable to predict the contribution of each of the sources using the multiple linear regression model (MLR). The PCs results showed that the sources of pollution are storm water runoff, industrial effluent, erosion and municipal waste, while MLR identified storm water runoff (0.786) and industrial effluent (0.241) as the respective major contributors of pollution. The study showed that the PC-MLR model gives a good prediction (R2=0.8) for the water quality index.